Study of Compounds: Hydrogen Chloride
Prescribed Textbook: Selina Concise Chemistry (Class 10) - Chapter 8
📖 Syllabus Scope & Overview
Laboratory preparation of HCl gas from NaCl and concentrated H₂SO₄ (< 200°C), drying agent (conc. H₂SO₄; why CaO and P₂O₅ cannot be used), collection by upward displacement of air, Fountain Experiment demonstrating high solubility and acidic nature, preparation of hydrochloric acid using inverted funnel arrangement (prevents back-suction), and chemical tests for HCl gas and chloride ions.
💡 Core Concepts & Curriculum Outline
Master the fundamental theoretical framework and syllabus scope approved by CISCE.
Laboratory Preparation of HCl Gas
Reactants: Sodium chloride (NaCl) and Concentrated Sulphuric Acid (H₂SO₄). Temperature maintained BELOW 200°C: NaCl + conc. H₂SO₄ (<200°C) → NaHSO₄ + HCl↑. Reasons: (1) Fuel is saved, (2) Apparatus does not crack, (3) Hard sodium sulphate (Na₂SO₄) crust does not form (which sticks to glass and is difficult to remove). Drying agent: Concentrated H₂SO₄ (acidic). Quicklime (CaO) and P₂O₅ react chemically with HCl and cannot be used.
Fountain Experiment & Inverted Funnel Arrangement
Fountain experiment proves that HCl is extremely soluble in water (1 vol water dissolves ~452 vol HCl) and is acidic (blue litmus turns red fountain). Inverted funnel arrangement provides larger surface area for absorption and PREVENTS BACK-SUCTION of water into the generating flask.
🔑 Mandatory ICSE Examiner Technical Keywords with Detailed Description
Official CISCE Evaluation BenchmarkAccording to CISCE board marking schemes, evaluators allocate marks based on the explicit presence of mandatory technical keywords. General or colloquial explanations fail to secure full marks. The table below details every required technical term, its scientific/academic description, the evaluator directive, and its exact model answer usage.
"Temperature < 200°C"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Temperature < 200°C" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Temperature < 200°C" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Laboratory Preparation of HCl Gas, ensure "Temperature < 200°C" is explicitly stated in the balanced explanation."
"Formation of sodium hydrogen sulphate (NaHSO4)"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Formation of sodium hydrogen sulphate (NaHSO4)" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Formation of sodium hydrogen sulphate (NaHSO4)" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Laboratory Preparation of HCl Gas, ensure "Formation of sodium hydrogen sulphate (NaHSO4)" is explicitly stated in the balanced explanation."
"Dried over concentrated H2SO4"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Dried over concentrated H2SO4" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Dried over concentrated H2SO4" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Laboratory Preparation of HCl Gas, ensure "Dried over concentrated H2SO4" is explicitly stated in the balanced explanation."
"Quicklime CaO is basic and cannot be used"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Quicklime CaO is basic and cannot be used" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Quicklime CaO is basic and cannot be used" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Laboratory Preparation of HCl Gas, ensure "Quicklime CaO is basic and cannot be used" is explicitly stated in the balanced explanation."
"Extreme solubility in water"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Extreme solubility in water" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Extreme solubility in water" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Fountain Experiment & Inverted Funnel Arrangement, ensure "Extreme solubility in water" is explicitly stated in the balanced explanation."
"Red fountain with blue litmus"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Red fountain with blue litmus" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Red fountain with blue litmus" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Fountain Experiment & Inverted Funnel Arrangement, ensure "Red fountain with blue litmus" is explicitly stated in the balanced explanation."
"Inverted funnel prevents back-suction"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Inverted funnel prevents back-suction" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Inverted funnel prevents back-suction" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Fountain Experiment & Inverted Funnel Arrangement, ensure "Inverted funnel prevents back-suction" is explicitly stated in the balanced explanation."
"Large surface area for absorption"
In ICSE Class 10 Chemistry (Study of Compounds: Hydrogen Chloride), "Large surface area for absorption" denotes a critical reaction condition, bonding mechanism, stoichiometric rule, or analytical observation required by CISCE.
Examiners award marks specifically when "Large surface area for absorption" is included alongside balanced chemical equations, observable color changes, or state symbols (s, l, g, aq).
"During the reaction in Fountain Experiment & Inverted Funnel Arrangement, ensure "Large surface area for absorption" is explicitly stated in the balanced explanation."
📝 Solved Textbook & 5 Generated Practice Exercises
Open Dedicated Exercise Page (class10_chemistry_solved_exercise_study_of_compounds_hydrogen_chloride.html) →Complete step-by-step evaluator solutions for textbook problems and 5 generated practice sets adhering to CISCE marking schemes.
(i) State the fundamental law or rule governing "Laboratory Preparation of HCl Gas". [1 Mark]
(ii) How does this concept change with temperature / pressure / time / scale? [1 Mark]
(iii) State one common mistake students make in this chapter and provide the correct scientific reasoning. [2 Marks]
(a) Predict what happens to the expected outcome if the boundary condition fails.
(b) Give complete scientific justification.
(c) State the critical safeguard or correction formula to rectify the error.
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